My hobbyist, non-EE understanding is as follows:
In many units when they are first turned on using the power switch, there is a spark that crosses the gap between the two contacts inside the switch. After the contacts are touching, there is much less chance of a spark. The spark can causes oxidization, a kind of burnt residue (which DeOxit is designed to help dislodge), and it can cause severe pitting of the contacts. The same is true for speaker protection relays.
The difference between relay contacts and power switch contacts is the amount of voltage and amount of current going between them and something called inrush.
Inrush current is a (typical) huge spike of current, at 120 or 240 V depending on where you live, that only happens at power on. The power reservoir capacitors "need" to be filled, they are commonly pretty big, and the power switch has just given them access to the big fire hose of voltage and current that is your house AC. These capacitors want to fill quickly, they "ask" for lots of power, and the still-closing power switch accommodates with as much as the wall socket AC and your power fuses will allow. That inrush is fine, is normal, but it makes that initial contact-gap-closing power switch get a bigger, stronger spark... causing more oxidization and pitting.
There are some good articles here on AK, one in particular, on avoiding this problem completely by adding a simple TRIAC circuit to your unit. The power switch gets reassigned to switching on and off a much lower voltage and negligible current which then controls a TRIAC where the main power flows. The TRIAC is solid state, so no sparking and the original power switch never gets asked to pass much and therefore little or no spark.
http://www.audiokarma.org/forums/in...or-so-of-your-time.504673/page-2#post-6897970