I spray head gaskets with K&W Copper Coat. All of 'em. Even those Teflon Fel-Pro head gaskets. Especially good on the popular multi-layer gaskets like Cometic. I have reused the Cometic head gaskets on the race car a bunch of times, just wash 'em and use a generous coating of Copper Coat. It's almost 14-1 compression.
I wouldn't think twice about using a copper shim under the head gasket. I would use a sealer, though. The manufacturers for copper head gaskets supply them with silicone. It's UltraGrey from Permatex in a no-name tube. I still swear by the K&W spray. I've used it on just about every engine you can think of, from a straight-8 Buick to a blown injected race engine.
If the shim is bothering you check out what many OEM gaskets look like nowadays.
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