usually you want bipolar capacitors in a crossover. Personally I'm not convinced the "audio" caps are anything more than standard low leakage ones with a fancy label. They don't have a real datasheet though, so thats hard to prove. The very fact that they do not have a proper datasheet makes me not real inclined to use them.
Reason its probably brighter has to do with reduced ESR. Poly caps are much lower ESR than electrolytic, so you get less voltage loss in the cap. You can add a small amount of resistance after the cap in order to restore that if you'd like. Probably wouldn't take more than an ohm.