Yes, sort of.
Some toroidal core power xfmers can be modified to make good output transformers, or used as-is successfully in the right circuit configuration. You need low plate impedance output tubes as a start, and you have to keep DC either out of the core as possible in a parafeed design, or cancelling as in a P-P design. Cathode coupling more normal Hi plate Z output tubes is a good possibility for using a standard toroidal power xfmer. Underrate the VA by at least 100% for every octave you wish to go below 60Hz as a minimum. 20-25% of the labelled VA is probably OK for 20 Hz.
The steel in high grade laminated E-I cores is better in good output transformers, and they use thinner laminations than in mains driven power transformers. Interleaving of windings is also necessary for a good product. There are so many things going on that it is a 'black art' as viewed fromoutside. Fun to play with but if you need guaranteed performance and cannot invest a lot of time just go buy one.