All of your can caps voltages are at least 50V higher than nominal. Tube load (how well they load down the circuit, mainly output tubes ) has a good deal to do with what the voltage is in the end. If the output tubes are old and weak, they won't have a lot of current draw and the voltages will be higher than normal. Are the output tubes you are using good, as in not weak? Remember in some cases tubes can sound quite good right up to the moment they die. Others can test weak and still produce fairly good sound, but are being highly stressed. So make sure your output tubes are up to snuff. Tubes MUST be inserted when checking voltages. If they are not installed, the voltage will be high, as shown above.
Pins 1&3 of V5 and V6 feed off the same CAN CAP Section. C3b is your source. Check the voltage there against the schematic. Then physically check the wire from C3b for open sections of insulation, pinched wire under mounting nuts, etc. Also pull one side of the following resistors and check for value. R45 & 46 (68K), and R47 & R48 (680K). Also make sure nothing is touching another component or chassis.
Overall I don't see anything glaringly wrong other than higher than normal B+ voltages from the 1st section on out, which would indicate to me that either the output tubes are not biased correctly, or they are weak and not drawing down the system like they should, or 1 or more bad CAN CAP sections.