Welcome.
Don't be so quick to remove the opamps. You've gotten superior tubes already over the stock ones. It might be of benefit initially to do the tape loop in deciding. Then you can go the Main-in/Pre-out route, where everything will be colored with the Tube 03, including the phones, I believe (but someone else might want to chime in on that).
I would not change any of the settings you presently have on the NAD. Insert the Tube 03 using the tape loop and set the tone controls on the Tube 03 at neutral, which I believe is 12 o'clock. Back the volume of the Tube 03 all the way off and gradually bring it on to your normal listening level. See how it sounds in and out of the loop. Play with the tone controls a little until you find what you like. If it's neutral that you like best, then you can remove the the tone opamp. It does provide a little gain so you're going to have to bump the volume of the NAD a bit to compensate. Also, before removing either of the opamps, experiment with bumping the volume up a little on the Tube 03 and backing off the NAD a little to see if you get more color from the Tube 03. If you like the sound with the tone controls, tho, there are superior opamps to the stock ones that with a small investment can improve the sound a lot. There are some that have mixed the brands of opamps, even; and others who have removed just the tone opamp and left the volume one or simply removed both. Lots of options and investigation for you.
Lastly, almost everyone on here has a linear power supply. Something like this:
https://www.amazon.com/Universal-Compact-Bench-Power-Supply/dp/B00069RB1Q/ref=sr_1_2?crid=14NECRYY0K7ZQ&keywords=pyramid+power+supply+12v&qid=1659361255&sprefix=pyramid+po,aps,168&sr=8-2
Small investments in tubes, opamps, and a power supply have turned this gem that PG began discussing years ago into a powerhouse. Good luck.