http://manuals.harman.com/JBL/HOM/Technical Sheet/S99 ATHENA ts.pdf
You have acquired a pair of one of the best and most versatile woofers available. If they have not already been refoamed, they will need that, as the original Lansaloy surrounds (ivory-colored) are likely hardened from age. You'll not get decent bass response from them until that is remedied. Use "Search" to find several discussions of S99 and LE14A refoam in this forum.
The mounting screws for the LE20-1 tweeter are behind the black foil covering the face, which may be carefully removed using a heat gun or hair dryer and a thin blade. Be careful not to crease the foil if you intend to reuse it. Neither new units nor factory replacement diaphragms are available for LE20-1. If one is actually bad and your intent is to restore, you'll have to replace it with a used one. They are quite common.
So much for restoration; on to upgrade:
LE20-1s hardly even qualify as tweeters by contemporary standards. They roll off significantly in the very high frequencies they might be assumed as purporting to reproduce:
If you want vintage sound with rolled-off highs, that's LE20(-1) in spades.
Can they be replaced with modern tweeters? Yes, probably, but modern tweeters which play competently down to S99's 2 kHz crossover frequency are rare. I believe I have further demonstrated in other threads here that, with respect to tweeters, in detail, "Plug 'n' Play" is somewhat of a mythical pursuit in vintage systems.
There's also another problem: S99 is one of several vintage JBL systems which earned for LE14A an undeserved reputation as haviing "muddy" midrange, and the reason is that it is misapplied in these systems. It's a large woofer with a heavily Aquaplas-damped cone for which 2 kHz is a lengthy stretch. LE14A is most suitably used up to 1 kHz, i.e., an octave lower. It can be pushed a bit above that, but not to 2 kHz.
So, what is the answer? You've got a system with a tweeter which plays neither high nor low enough mated to a woofer that doesn't play high enough to match it. Member Jackgiff made them into three-ways here:
http://audiokarma.org/forums/showthread.php?t=119471
I have a more radical approach:
http://audioheritage.org/vbulletin/showthread.php?t=7671
As an extension of that concept, both Jackgiff and member Duffinator have completed projects incorporating LE14As and PT waveguides in other cabinets:
http://audiokarma.org/forums/showthread.php?t=117212
http://audiokarma.org/forums/showthread.php?t=136160
Member Mxlews is using LE14As as subs in Altec Madrid cabinets, though he has not yet shown us that project here.
Otherwise, restore them and enjoy what they are.... :thmbsp: