Without working out a schematic of whatever power supply modifications were done to your unit, it's going to be difficult to sort out what's going wrong. Are you getting the same voltages on both 7199s, or just V2?
That missing resistor in the negative rail is probably causing the greater voltage there.
Most of those voltages are within a reasonable tolerance of the specified values. The ones that are off are way off, though. Are R103 and R104 in place and of the correct values? I think they'd be the first things I'd check considering the weird voltages on both sides of the V2 triode section. If one of them is an incorrect value or damaged, or there is a bad solder joint somewhere, that could be causing some of the weirdness. I'd check R101, C102, and R106 as well, as they're also acting directly on that triode section.
The 22k resistor between the bias pot and the negative rail was eliminated in the Nov. 62 schematic with the redesigned power supply. The TSB mentions removing it and installing a jumper wire.
.22uF should be fine for the coupling caps. One of my long-running questions that I keep going back and forth on regarding my slow rebuild is whether to use .22uF NOS Soviet K40Y PIO coupling caps, or paired .15uF and .10uF Sprague Vitamin Q PIO caps to get right on the specified .25uF value. Most of the gurus seem to think that either is fine. I'm considering trying one version in one channel, and the other on the other side in order to compare results. 400V or 450V parts might be a bit low, that doesn't leave you with much tolerance if there is a spike. .22uF 1000V caps are pretty readily available and not terribly expensive, both in film and PIO forms. .22uF 500V are very common. There are usually lots of NOS Soviet K40Y and K42Y PIO caps on eBay, and they make very nice coupling caps for tube amps.
I fixed that pin 4/9 thing on the schematic and sent it to the AK database moderator.
Another thought: you might look at the original assembly/operation manual and pictures of the underside of working amps to figure out if there is an issue with the cap positioning that's adding to the hum.