I believe that Wharfedale or Lowther was the first commercial user of foam. Gilbert Briggs of Wharfedale was a remarkable listener, designer, author(!) and businessman. He discusses his use of isocyanate foam in both Audio A to Z and Loudspeakers. When first introduced, the surrounds were flat because the foam was so stretchy that a roll was not necessary. But the foam wasn't long term stable, and I doubt any of it survived many years.
Lowthers had foam surrounds and spiders, and the spiders seem to have survived fairly well, perhaps because they are fairly thick and not likely to be hit by sunlight.