As with other materials in this hobby, such as various metals used for plugs and conductors and their (IACS) conductivity rating from least conductive to most conductive and whether they are alloys or pure metals, there's also a hierarchy of film materials used as insulators or dielectrics to help implement the function of a cable or capacitor. When an insulator makes direct contact with a conductor, there are some negative effects and interactions that occur- namely dielectric loss and added capacitance to the signal. Because of this, what goes in is not equal to what comes out. However, it is very close. For instance, unless you had a bare speaker wire from I/O with no insulator surrounding it, the sound is being somewhat colored by the insulator in contact with it when the speaker receives the signal. This is because an insulator interacts with and leeches the signal of the conductor to a small degree. It is a necessary evil we have to put up with. Unless you are "listening" for this, this phenomenon does not really matter outside the audio realm as far as I'm aware. While there is science to back up this notion, it mostly only matters for audio reproduction, specifically regarding "sound".
However, some films perform better than others. Not necessarily in the sense they're adding something "magical", but that they aren't taking as much away -or coloring the sound as much, think "EQ". Many films add a slight overlay or veil to the sound. Teflon/ptfe is a good example of a superior film that is better than most other alternatives -just slightly above polypropylene. Because of this, teflon capacitors are generally regarded as best-in-class. This could matter in a speaker crossover or coupling cap (for instance) among other applications such as choosing wiring/ cabling insulated with these better film materials for less interaction/ degradation of the sound. From my own trials and empirical experiments, a film with a dielectric constant (K) of 2.XX or less sounds better than a film with a higher-K than this. Some examples of films with a relatively higher-K compared to the best alternatives would be acrylic, vinyl, polyvinyl chloride (PVC), polyester and all its derivatives. I've always liked the sound of mylar the most of all polyesters which makes sense, considering it has a lower K (3.1) than base polyester (3.6). Somewhat related, and take it fwiw, regarding a "cable break-in period", insulator molecules may draw energy from the conductor, re-arranging themselves (and the conductor itself) into a more uniform structure over time.
Some examples of films with lower-K include teflon/ptfe, polystyrene, polypropylene, PE (among others). There are even mixtures, such as PE Foam, or other films made into "foam insulation" cable material. The advantage of this is that the tiny air bubbles injected into the film have a K of only 1, so when combined with a low-K film, the resulting K is even lower than its base film material (but still not quite 1 which is the reference point for air/ vacuum). Other materials besides film that make good insulators for cables/ wires include cotton, air (as mentioned) and perhaps others.
Long story short, whenever you are able to choose film materials with a lower dielectric constant of around K=2.XX (or less) the sound will be truer to its source. Plastics make it possible.
Dielectric constants (averaged) of commonly used films/ materials in audio:
Air = 1.006
Acrylic = 3.1
Butyl Rubber = 2.3
Cotton = 1.3
EPR = 2.2
FEP = 2.1
Foam PE = 1.6
Fluoropolymers = 2.0
MPPE = 2.2
Mylar = 3.1
Oil = 2.4
Paper = 3
PE = 2.3
PFA = 2.1
Polyester = 3.6
Polycarbonate = 3.1
Polypropylene = 2.2
Polystyrene = 2.6
Polyurethane (PU) = 1.1
Polyvinyl Chloride (PVC) = 3.6
PPS = 3
Silicone = 2.8
Teflon/ptfe = 2.1
TPE = 2.2
Vacuum = 1
Vinyl = 4
XLPE = 2.3
However, some films perform better than others. Not necessarily in the sense they're adding something "magical", but that they aren't taking as much away -or coloring the sound as much, think "EQ". Many films add a slight overlay or veil to the sound. Teflon/ptfe is a good example of a superior film that is better than most other alternatives -just slightly above polypropylene. Because of this, teflon capacitors are generally regarded as best-in-class. This could matter in a speaker crossover or coupling cap (for instance) among other applications such as choosing wiring/ cabling insulated with these better film materials for less interaction/ degradation of the sound. From my own trials and empirical experiments, a film with a dielectric constant (K) of 2.XX or less sounds better than a film with a higher-K than this. Some examples of films with a relatively higher-K compared to the best alternatives would be acrylic, vinyl, polyvinyl chloride (PVC), polyester and all its derivatives. I've always liked the sound of mylar the most of all polyesters which makes sense, considering it has a lower K (3.1) than base polyester (3.6). Somewhat related, and take it fwiw, regarding a "cable break-in period", insulator molecules may draw energy from the conductor, re-arranging themselves (and the conductor itself) into a more uniform structure over time.
Some examples of films with lower-K include teflon/ptfe, polystyrene, polypropylene, PE (among others). There are even mixtures, such as PE Foam, or other films made into "foam insulation" cable material. The advantage of this is that the tiny air bubbles injected into the film have a K of only 1, so when combined with a low-K film, the resulting K is even lower than its base film material (but still not quite 1 which is the reference point for air/ vacuum). Other materials besides film that make good insulators for cables/ wires include cotton, air (as mentioned) and perhaps others.
Long story short, whenever you are able to choose film materials with a lower dielectric constant of around K=2.XX (or less) the sound will be truer to its source. Plastics make it possible.
Dielectric constants (averaged) of commonly used films/ materials in audio:
Air = 1.006
Acrylic = 3.1
Butyl Rubber = 2.3
Cotton = 1.3
EPR = 2.2
FEP = 2.1
Foam PE = 1.6
Fluoropolymers = 2.0
MPPE = 2.2
Mylar = 3.1
Oil = 2.4
Paper = 3
PE = 2.3
PFA = 2.1
Polyester = 3.6
Polycarbonate = 3.1
Polypropylene = 2.2
Polystyrene = 2.6
Polyurethane (PU) = 1.1
Polyvinyl Chloride (PVC) = 3.6
PPS = 3
Silicone = 2.8
Teflon/ptfe = 2.1
TPE = 2.2
Vacuum = 1
Vinyl = 4
XLPE = 2.3
Last edited:

wooden capacitors.