Electrolytic capacitor design and construction
After catching up on the ongoing discussion here, it seems apparent that some (Kjell-B) still want to deny the science and reality of electrolytic capacitor construction. So, my planned post on "subjective" evaluations and experience after "totally" re-capping over 300 audio units will have to wait.
I would refer any new readers to my first fact post #61 and to Morden2004's post #101 especially noting his attachment which shows the physical construction of an electrolytic capacitor.
Now if you have read those..........then the following will make sense:
Electrolytic capacitors when used in power supply (both High and Low voltage) are virtually identical to your car battery. They include a charged plate, and ELECTROLYTE in either a liquid or paste formula.
So let me pose the first question regarding their construction:
"Why does Nichicon rate their life expectency at 15 years MAXIMUM and shorter depending on use and ambient temperature"?
The answer is found in Morden2004's post #101 attachment. It is primarily because of two reasons:
1) The capacitor contains electrolyte in either a liquid or paste form! Over time the electrolyte will EVAPORATE!! This evaporation process while varying slightly in the time it takes to occur.......HAPPENS irregardless of whether the unit it is installed in operates daily or is simply in storage.
ESR and its change in a specific cap is dependent on the conductivity of the electrolyte. When "new" and the electrolyte is still in a liquid or paste form........it is low. This is easy to understand as you can just think of it as passing an electric charge through water or any liquid. Once the electrolyte has evaporated...........you are now trying to pass an electrical charge through what is really more like "concrete" than liquid.
2) The only way to prevent evaporation is to SEAL the cap...........which again referring to the construction of electrolytic capacitors you will find that they all MUST include a "VENT". Why? Very simply because depending on the AMBIENT temperature and the electrical charge passing through them......... they give off gas and expand/contract depending on temperature. If they were sealed.......they could explode or bulge when expanding. Their vent allows them to expand/contract as needed to maintain stability.
So from the above we can add a new FACT to this thread:
FACT: All electrolytic capacitors are subject to evaporation of their electrolyte whether in use or in storage.
The only possible question to this is "How long does it take for the electrolyte to evaporate enough to affect performance"? And the answer is found right in Nichicon's chart:
FACT: The MAXIMUM storage life is 15 years even if the unit has NEVER been turned on.
Anyone that wants to deny or ignore these facts does so at their own risk (and unfortunately the risk of their equipment!!) But, this isn't rocket science gentlemen.........
Based upon the above it can also be easily determined that if someone says they prefer the "original" sound as designed by the Manufaturer they also have to recognize that:
1) The original design utilized "new" caps with liquid or paste electrolyte present in every electrolytic cap. So, if TODAY you wanted a true experiment as to what a specific piece sounded like....all you have to do is:
A) Find a "new in the box" never used piece.
B) Totally "re-cap" it and replace every electrolytic capacitor in it.
In looking on the internet for scientific examination of electrolytic capacitors I found the following analysis which is directly on point for our discussion here:
Nuclear Regulatory Commission said:
Having found that Nuclear Safety Related units had the capacitors installed IRI issued a verbal notification of the 10 CFR 21 report on January 22, 1999 at 1420 CST and was issued and incident number of 35,304. IRI also verbally notified Mr. M. Reno (NYPA) and W. Brian Barrett (NIMO) of the 10 CFR 21 report and the models and serial numbers of the units that the capacitors were insulted in.
Attachment 2, is the complete list (Nuclear Safety Related and Non-Nuclear Safety Related)of all units identified during the IRI records search that contain the 9322H date coded capacitors. IRI will transmit this list to each of the affected utilities, with this report, for all of the affected modules.
Failure analysis of the capacitors at BMI found that "...all of the parts were very dried out, and there was basically no electrolyte left. The seal bead dimension on all five parts measured 0.225". This is slightly larger than the current specification of 0.205 +/-0.008. Four of the five capacitors anode wire was broken internally, but it could not be determined what caused this failure. However, the fifth capacitor was not severed, but was still dried out. This is why we feel the root problem of the failures was the drying out of the capacitors."
(See Attachment 1 for the full letter from BMI).
CONCLUSION AND RECOMMENDATIONS
IRI has concluded that the Sprague model TE1302 capacitors with a date code of 9322H were manufactured with an end seat bead that was larger than specifications currently allow, the end seal allowed the capacitor's electrolyte to dry out (offgas) in an accelerated manner, causing the capacitors to fail in an accelerated manner. The failure mechanism of the capacitors are in the normal manner of all aluminum electrolytic capacitors, drying of the electrolyte which results in increasing equivalent series resistance (ESR) leading to increased heating of the electrolyte, leading to increased electrolyte drying, leading to increasing ESR, until the electrolyte is totally dried out and the capacitor fails.
IRI recommends that these capacitors be replaced as soon as practical. Since these capacitors have served over 60% of the expected shelf/useful life of the aluminum electrolytic capacitors IRI recommends that the modules that they are installed in be totally refurbished and all aluminum electrolytic capacitors in the modules replaced, during replacement of the affected capacitors.
You can subjectively debate different capacitor brands and their subjective sound quality..........but to try and debate the above information or claim that electrolytic capacitors can last for "500" years.........is a simple denial of reality. And, that too is a
FACT.
QB
ps: Paul this thread really should be a sticky. At least those posts regarding electrolytic capacitor theory, construction and operation in "vintage" audio equipment. And, please don't close it yet.......I hope to have a statement regarding audio signal path caps and what they do to audio signals later this weekend.