Well according to a room size calculator, and assuming the ceiling is a standard 8 ft, your room is close to one optimized size of 10’ 3” by 12’ 4”.
Your 14 foot wall is long, but a floor to ceiling heavy curtain on the back wall with the door, might be used to shorten it and cover the pocket the doorway leaves, as well as cut the reflection off the back wall.
Speaker placement is very dependant on the speakers, some need to be in the corners by design, some need to be on a wall by design, and many benefit from being off the back wall and away from the side walls.
A starting point I keep hearing is 3 feet from the side walls, but that has to be for a larger room. This would place you the listener at about 4 feet away, so I’d start at 2 feet, leaving 6 feet spacing of the speakers, and you about 6 feet away, assuming you are using the last type of speakers.
Don’t be afraid to play round with placement, and the toe of the speakers. I usually wind up pointing then just outside my ears, not directly at me, and not perpendicular to the back wall for best imaging.
That space behind the big curtain could cover the gear, record storage, or whatever.
I’ve been thinking about the designs on the older theaters, after the gaudy age and before the current crop. They often had curtains or curtain like treatments on the walls all around. I wonder if they were onto something with this.
It might be interesting to try if the materials could be had cheap/free. Maybe a custom curtain shop might have either castoffs or curtains that were made wrong. (I worked at a custom drape shop in HS for a short time, it happened fairly often, or someone orders and never pays…)