Alright, back at it again today. I read up on amplifier design to try to at least get a better sense of what components do what so I can have a better idea of what might be the trouble spot.
With that, I thought it would be worth while to hook the output of the amp to an oscilloscope to check if I could see what I thought was the crossover distortion, or if maybe its distortion created from the VAS. Either way, still thinking it's likely some kind of bias issue. To my surprise, I wasn't seeing any distortion at all, but when I switched back to the speakers the distortion was still pretty evident. So Natural next step was to look at the output under the load, and long behold, with the speakers hooked up, I could see the distortion clipping the negative swing of the sine wave. Evidently, not crossover distortion. Moving over to my dummy load showed an even sharper clip of the sine wave, and if I brought the volume up, it would even throw the unit into protection mode.
With that my next step was to re-measure my voltages under this condition. I've attached an image of the clipping on the oscilloscope, as well as my updated voltages, running an 8-ohm dummy load with a 100Hz sin wave at 1.01V into the aux input. Now things are really out of hand. Looks to me like the -90 volt rail is loading up pretty severely, throwing everything else off. As I bring the volume up, the negative voltage on that rail continues to drop. The output stage I'm guessing is actually solid, and it's either the input or voltage amplification stage.
I'm thinking my next step is still to just start pulling components and testing each individually, but I'm interested to hear what everyone else is thinking with this new development... Also not sure if it was a rookie move to be testing without a load from the start, but hey, you live and learn.