So are Solid State though perhaps in a slightly different way.
When you get down to fundamental parameters, the average single transistor is inherently more flawed (less linear) than the average single tube...
Just look at the transconductance curves- the tube curves are, on average, much closer to straight lines than the transistor curves. In essence- a single tube, by itself, without feedback, "bends" the sound LESS than a single transistor.
This is one reason why transistor amps require much more feedback than tube amps, to reach a decent level of linearity. And that feedback comes at a price- the creation of upper harmonics is one (not the only one, but a very significant one) of those.
The one good thing about transistors, is that they are SO cheap, that MANY of them can be used- in essence, to create enough gain that the feedback can be incorporated in high enough level to "force" the response to be linear, down to what, on paper, are very low levels of "total" distortion. However, when one looks at the harmonic structure of the distortion- a tube amp's distortion pretty much is confined to the lower harmonics (closer in frequency to the original signal), while transistor amps have audibly significant (and the levels to be significant can be VERY low from an audibility sense, at the higher harmonics) levels of these higher harmonics- harmonics actually CREATED by the feedback itself- once the action of the feedback loop is factored in. In essence, the farther the overtone is from the original fundamental, the more it is audible at the same level.... which can be problematic with high-feedback designs of any type...
It is possible to build solid-state amps with improved distortion behavior- but that's usually not going to happen with the traditional class-A or class-AB topologies. And it's difficult with the class-D and other alternative-tech solid-state amps as well- but people are figuring out ways to make that work better, as we go on...
Regards,
Gordon.