I'm with you, I think experimentation for the sake of learning is what has made this hobby so popular. But I must caution you, you're standing at the top of a deep rabbit hole.
While some may think the no highs / no lows is a bad thing, there is an upside. When properly EQ'd and fed sufficient power they can be listend to for hours and hours at very high levels without becoming fatiguing. Not many other speakers can do that.
On key is sufficient power. With all those individual drivers and the extreme boost applied by the EQ the 901's suck up some serious current. While the Spec series of Pioneer is certainly some nice gear, it is not a particularly high current design and that may be the achilles heel of your setup. Since this is an experiment, I'll leave you to discover that on your own.
The other items that will greatly impact your experiment are the selection of your subwoofer and high frequency drivers. Soft dome, hard dome, horn loaded, paper cone and other tweeter designs all have their compromises, which ones fit your experiment will take some time to sort out. Subwoofers are a rabbit hole all on their own. I prefer smaller driver, high power, sealed enclosure subs(plural) YMMV.
Always remember, YOU are the only one who has to like what your system sounds like. We all hear and listen differently, different rooms, different gear, different music, in the end your system has to work for you.
Carry on my good man. Enjoy yourself and keep us posted on your progress.