I did some modeling on the 222D in Duncan PSUD2.
Since the 222D has a 20 ohm 10w resistor immediately after the 5AR4, that "cushions" the rectifier from current spikes a bit, making it possible to stretch the normal capacitance limit for the 5AR4, a bit.
I found, that if you use a SINGLE 100uf section to replace BOTH 20uf parallel sections at the output of the 20 ohm 10w resistor (going from 40uf to 100uf), the rectifier will still be within spec (does not exceed .75a max peak current, rated for the tube). But, just barely. In case of rectifier arcing, you can replace the 20 ohm 10w resistor, with one between 33 and 40 ohms (still 10 watt), and it will reduce the peak loading on the rectifier by about 10%, while only dropping a max of about 12v from B+ (hardly noticeable, if at all, in terms of peak power output of the amp).
The can caps in this amp should either be a 4-section 20uf and a 2-section 20uf, or two 3-section 20uf caps... for a total of six 20uf sections. If those are replaced by two 100uf 2-section caps... then, one more section will be needed. You can replace the 20uf x 2 paralleled section with one 100uf as mentioned above, and the next three 20uf sections with the remaining three sections (one in the first cap, both in the second cap), but you will need one more cap (say, 47uf at 350v or so, mounted under the chassis) to replace the last one in line. Here's the original power supply diagram for the 222D, modified to show this arrangement:
This should work OK...
Regards,
Gordon.