Something that the OP may not have considered is the large difference in sensitivity between the two pairs of speakers she intends to run simultaneously.
This may not be as much of an issue if they are in two separate spaces, but in any case she should be aware that one pair (the Klipsch, at 96dB/1 watt) will be nearly twice as loud as the other (ADS at 87dB/1 watt).
If she moves forward with a separate power amp to drive the second pair, it might be advisable that this amp have its own gain control. This would allow her to "synchronize" the volume of the two pairs of speakers...after which, of course, she would use the volume control on the Pioneer receiver (assumedly being used as the preamp for the external power amp) to control the loudness of both pairs of speakers.
I would recommend driving the ADS speakers with the external power amp; otherwise the gain on the external power amp might have to be set so low as to cause problems.
To the OP - Speaker sensitivity ratings allow you to compare the relative loudness of one speaker vs another, when given equal power (1 watt). Your speakers have a difference of 9 decibels (dB). That translates, roughly into "the Klipsch will be twice as loud as the ADS". This will be true at all volume settings. Effectively, the ADS speakers need 8 times the power needed by the Klipsch to achieve the same loudness!
As mentioned above, if your power amp has its own gain control, you can use it to boost or attenuate the loudness of the speakers connected to it, so that both pairs (the ones driven the by the external amp and the pair driven by the power amp section of the SX-1080) have approximately the same output (that is, the same loudness).
Good luck.