Anyone remember the debacle when XBox's where using lead-free solder? I bought a XBox around that time, had to send it back for repair after about one month. It lasted about another 3 months and fizzled out.
Solder selection depends on application. If I needed a high reliability electrical connection, such as in a nuclear weapon, I would use silver solder if the circuit ran hot and had to survive other environmental conditions, such as sitting for 20 years in a unheated/cooled vault.
For most uses at home, such as stereo gear, the 1mm diameter lead/tin solder is perfect. Lead and tin are used because when heated, a eutectic point is reached with regards to temperature. In other words, if the solder contains a certain percentage of lead to tin (Pb/Sn), the alloy melts at a lower temperature than lead or tin would by itself. When you are soldering, you want to join two conductive metals together so that they will stay together despite being heated and cooled during operation of the circuit. One advantage to using a solder with a mixture of silver is that the circuit could withstand higher temperatures since the eutectic temperature would be higher with solder containing silver. Many military and aircraft electronics use a solder containing silver because the goal is that the electronics survive and are reliable under much more extreme conditions than lead free and Pb/Sn solders.
Solder selection depends on application. If I needed a high reliability electrical connection, such as in a nuclear weapon, I would use silver solder if the circuit ran hot and had to survive other environmental conditions, such as sitting for 20 years in a unheated/cooled vault.
For most uses at home, such as stereo gear, the 1mm diameter lead/tin solder is perfect. Lead and tin are used because when heated, a eutectic point is reached with regards to temperature. In other words, if the solder contains a certain percentage of lead to tin (Pb/Sn), the alloy melts at a lower temperature than lead or tin would by itself. When you are soldering, you want to join two conductive metals together so that they will stay together despite being heated and cooled during operation of the circuit. One advantage to using a solder with a mixture of silver is that the circuit could withstand higher temperatures since the eutectic temperature would be higher with solder containing silver. Many military and aircraft electronics use a solder containing silver because the goal is that the electronics survive and are reliable under much more extreme conditions than lead free and Pb/Sn solders.
