Dynaco's FMX-3, a module intended to go into the FM-1 tuner.
S/C had a cool tubed unit, as did Eico, as Mark already mentioned.
Fisher had the WX and MPX-65 drop in boards, and the MPX-100 and MPX-200 external decoders. There was also the MPX-10 for one of the failed FM stereo competitors.
I've never heard of a tube S/C multiplex decoder, just the solid-state unit.