The issue isn't (as far as I am concerned*) - it's robustness. The Mullards will last for years and years - most modern 5AR5s; not so much.
The 5AR4 was the most "high tech" vacuum tube HV rectifier developed, and it was developed principally for hifi use. It is very efficient (low voltage loss) and can deliver quite a bit of HV for its little package. There've been some poor performing variants - the classic Mullards, though, generally might be expected to last a lifetime (or more).
* Although it can be argued that everything in the sonics of an amplifier will ultimately trace back to the power supply.