Going from left to right, from the pictures above... tubes 1, 4, 5 and 6 are essentially the same tube (RCA). Blackplate vs. gray plate won't make much difference in the sound, IME.
2 and 3 are the odd ones out. If you can find one more tube somewhere, that matches either one of those, you can have another pair.
In that amp, there are three pairs. If you're looking over into the inside of the amp from the front (front panel closest to you), the far left two are, IIRC, the phono stage (I'd put tubes 4 and 5 there), the middle two are the preamp/tone stage (I'd put 1 and 6 there), and the right hand two (closest to the power transformer and rectifier tube) are the amp driver (I'd put the two mis-matched ones there, until you can match one or the other of them).
That should minimize any difference in sound, due to the tubes not being exactly the same...
Regards,
Gordon.