For many tubes the "A" was a controlled warm up, but actually in the 12AX7/12AX7A both were spec'd the same for filament warm-up.
The "A" was spec'd for low noise/hum. I believe there was no spec on the 12AX7, the 12AX7A was spec'd for < 1.8uv rms (as was the 7025).
You should be able to substitute in either direction without causing electrical problems. The 12AX7 "might" be noisier, but then again it might not....
- Gary