You are referring to reforming.
Here is a link if you want to learn a little more.
The thin aluminum sheets used in electrolytic caps form a layer of aluminum oxide when they are exposed to current in the presence of electrolyte. The layer must be in place for the cap to perform as engineered. It can work without, but just not as designed.
Over time of disuse the layer dissipates and the unit can perform in unexpected manners and sometimes fail. Caps older than the ones in 70s vintage equipment had worse failure modes, and that’s where some of the horror stories come from.
A cap must be exposed to electricity to form and keep the layer. If it dissipates, often it can be reformed. Some say that starting at a low voltage and working up to full voltage is the best way, and I have no reason to doubt this wisdom. I’d guess that doing caps out of circuit is probably optimal, but difficult. If I owned a Variac, I might indulge my rescued devices to this lab bench spa treatment, I dunno. That said, I have bought many vintage devices. Most have been tested before I ever see them (i.e., pulled out of the closet by the owner or heir after years, and plugged in by the seller to see if it works). I’ve not experienced a catastrophe failure because of an unformed cap. Since I don’t have a variac, I hook a new amp up to the DBT and turn it on, ready to turn it off at a sign of trouble.
To reform a cap in place, connect the unit to a Variac, add a resistor in series and turn it in. Then slowly (very) ramp up the voltage once it gets to full voltage, then let it sit for five mins plus 1 minute for each month in storage. So, if it’s been in storage for 10 years, a little over two hours should get you going. Or just let run on the DBT for a while.
Personally, I think looking for leaking caps is a better use of time. And I never leave a new piece of equipment alone until I’m sure it’s not going to burst into flame. I know of old radio restorers who have pretty serious little fires on units they are working on.
Once potential danger has passed, you can see if the protection relay clicks. If it does, you can check DC offset. It should be as close to zero as possible. If it’s under 50 to 90 milliamperes, it’s OK to hook junker speakers up to see how it sounds, although it is advisable to replace the differential pair transistors with a matched pair it it’s over 25 mv.
Then it’s time to listen and let us know how it’s doing.